应用化学2012，Vol.29Issue(11)：1251-1255,5.DOI:10.3724/SP.J.1095.2012.00547
1,1-二苄基-1,1-二硫乙酰腙甲烷类化合物的微波辐射法合成
Synthesis of 1,1-Bibenzyl-1,1-bimercaptoacetyl-hydrazonemethane under Microwave Irradiation
摘要
Abstract
Using 1,3-diphenylacetone as precursor, bibenzyldithiolmethane(1) was prepared through reacting 1, 3-diphenylacetone with dry hydrogen sulfide and hydrogen chloride. Under microwave irradiation, compound 1 was subjected to esterification and hydrazinolysis to yield 1, 1-bibenzy1-1, 1-bimercaptoacetyl-hydrazine (3). The condensation reactions between compound 3 and aromatic aldehyde led to the production of a series of 1,1 -bibeneyl-1,1 -bimercaptoacetylhydrazone (4a ~ 4n ). Their structures were confirmed by IR, 1H NMR, MS and elemental analysis.关键词
微波辐射/乙酰腙/合成Key words
microwave irradiation/ acetylhydrazone/ synthesis分类
化学化工引用本文复制引用
冯驸,崔治财,段正超,胡卫兵..1,1-二苄基-1,1-二硫乙酰腙甲烷类化合物的微波辐射法合成[J].应用化学,2012,29(11):1251-1255,5.基金项目
教育部重点项目(211111)和湖北省教育厅中青年项目(Q2011902)资助 （211111）
