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苯乙烯嘧啶化合物的合成及其作为pH探针的光谱特点

熊小琴 翟秋阁 薛灵芬 郑斐 谢旭

应用化学2012,Vol.29Issue(11):1262-1265,4.
应用化学2012,Vol.29Issue(11):1262-1265,4.DOI:10.3724/SP.J.1095.2012.00578

苯乙烯嘧啶化合物的合成及其作为pH探针的光谱特点

Synthesis of Styrylpyrimidine and Its Spectral Characteristic as a pH Probe

熊小琴 1翟秋阁 1薛灵芬 1郑斐 1谢旭1

作者信息

  • 1. 信阳师范学院化学化工学院 信阳 464000
  • 折叠

摘要

Abstract

4,6-Bis[ (4'-diethylamino) styryl] pyrimidin-2-ol was synthesized and characterized. The UV-Vis and fluorescent properties were studied in phosphate buffer solutions at different pH value. The UV-Vis spectral results indicated that the peak located at ~500 nm reaches maximal intensity at pH =6.78. The fluorescent spectra data suggested that the intensity of emission peak decreased with increasing pH value. The fluorescence was quenched when the pH was 5. 51.

关键词

苯乙烯嘧啶/pH探针/吸收光谱/荧光光谱

Key words

styrylpyrimidine/ pH probe/ absorption spectrum/ fluorescence spectrum

分类

化学化工

引用本文复制引用

熊小琴,翟秋阁,薛灵芬,郑斐,谢旭..苯乙烯嘧啶化合物的合成及其作为pH探针的光谱特点[J].应用化学,2012,29(11):1262-1265,4.

基金项目

河南省高校科技创新人才基金(2010HASTIT025)、河南省科技创新人才项目(104100510020)、河南省教育厅自然科学研究项目(2009A150023)资助 (2010HASTIT025)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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