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冷却水中缓蚀剂对贫铀的作用研究

蔡定洲 桑革 刘家汐 仲敬荣 郎定木

原子能科学技术2012,Vol.46Issue(z1):158-163,6.
原子能科学技术2012,Vol.46Issue(z1):158-163,6.

冷却水中缓蚀剂对贫铀的作用研究

Corrosion Inhibition Behaviors of Different Inhibitors for Depleted Uranium in Cooling Water

蔡定洲 1桑革 1刘家汐 2仲敬荣 2郎定木2

作者信息

  • 1. 表面物理与化学重点实验室,四川绵阳621907
  • 2. 中国工程物理研究院,四川绵阳621900
  • 折叠

摘要

Abstract

Inhibition effect of sodium nitrite and sodium molybdate combined with triethanolamine respectively for depleted uranium was evaluated in cooling water by weight-loss method. The corrosion surfaces of depleted uranium immersed in cooling water at different temperatures for 20 h were analyzed by laser Raman spectrum and scanning electron microscope (SEM). The results show that sodium nitrite and sodium molybdate have inhibition effect for depleted uranium. Inhibition efficiencies of the two inhibitors are improved by adding triethanolamine. Inhibition efficiencies of sodium molybdate combined with triethanolamine are 89% and 88% at 45 ℃ and 65 ℃ , respectively. Inhibition efficiency of sodium nitrite is 93.4% at 85 ℃. Uranium dioxide is main component on uranium surface determined by laser Raman spectrum. The analysis of SEM indicates that the oxidation film formed on uranium surface is compact in cooling water with inhibitors.

关键词

失重法/亚硝酸钠/钼酸钠/三乙醇胺/缓蚀剂

Key words

weight-loss method/ sodium nitrite/ sodium molybdate/ triethanolamine/corrosion inhibitor

分类

能源科技

引用本文复制引用

蔡定洲,桑革,刘家汐,仲敬荣,郎定木..冷却水中缓蚀剂对贫铀的作用研究[J].原子能科学技术,2012,46(z1):158-163,6.

基金项目

中国工程物理研究院所长基金资助项目(SJ201007) (SJ201007)

原子能科学技术

OA北大核心CSCDCSTPCD

1000-6931

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