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低阶煤O2/CO2气氛下燃烧生成颗粒物的特性

汪应红 王群英 付晓恒

中国电机工程学报2012,Vol.32Issue(29):52-58,7.
中国电机工程学报2012,Vol.32Issue(29):52-58,7.

低阶煤O2/CO2气氛下燃烧生成颗粒物的特性

Fine Particles Formation During O2/CO2 Combustion of Low-rank Coal

汪应红 1王群英 2付晓恒1

作者信息

  • 1. 中国矿业大学(北京)化学与环境工程学院,北京市海淀区100083
  • 2. 华电电力科学研究院,浙江省杭州市310030
  • 折叠

摘要

Abstract

Two kinds of typical low-rank coal were burned in a drop tube furnace under different atmosphere. The produced particulate matters(PM) were collected by the cyclone and low pressure impactor(LPI). Transmission electron microscopy(TEM) and scanning electron microscope (SEM) were used to identify the morphology of the super-micron and submicron PM. SEM with an energy dispersive X-ray(SEM-EDX), TEM with an energy dispersive X-ray spectroscopy(TEM-EDS) and computer-controlled scanning electron microcopy(CCSEM) were applied to analyze the chemical composition in the ash. It has been confirmed that compared with air atmosphere, O2/CO2 atmosphere changes the generated fine ash particle size distribution and the concentration of the chemical composition, but the formation mechanisms are same for different atmosphere. For the case of the lignite with more amount of organic-associated minerals, O2/CO2 atmosphere increase the vaporization degree of Fe, Na/K sulfates, Al and Si, and thus increase the concentration of sub-micron particles. Also Fe is found to be a key element in the lignite. Oxy-fuel-combustion increases the attachment of vaporized Fe element to other particle.

关键词

煤燃烧/矿物质/颗粒物/O2/CO2

Key words

coal combustion/ minerals/ particle/ O2/CO2

分类

能源科技

引用本文复制引用

汪应红,王群英,付晓恒..低阶煤O2/CO2气氛下燃烧生成颗粒物的特性[J].中国电机工程学报,2012,32(29):52-58,7.

基金项目

国家自然科学基金项目(50606035). (50606035)

中国电机工程学报

OA北大核心CSCDCSTPCD

0258-8013

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