中国造纸2012，Vol.31Issue(11)：25-29,5.
新型返黄抑制剂的合成及性能研究
Synthesis of a New Yellowing Inhibitor and Its Property
摘要
Abstract
Using cyanuric chloride as the crosslinking monomer, a new yellowing inhibitor for high-yield pulp was synthesized by introducing the ultraviolet absorber 2,4-dihydroxy-benzophenone and free radicals capturer 4-amion-2,2',6,6'-tetramentylniperidine to the same molecule of 4,4'-diamino stilbene-2,2'-disulfonic acid (DSD acid) through nucleophilicity reaction. Its structure and property were characterized by FT-IR, UV-vis and photoluminescence(PL) spectra, its anti-yellowing effect was evaluated by surface sizing on the handsheet of chemi-me-chanical pulps and evaluated by the ultraviolet aging apparatus. The results showed that comparing with the traditional fluorescent brighten-ers, such as VBL, the brightening effect and light stability of the new compound are good, the brightness stabilizing effect increases significantly and paper brightness has 9.4 ISO points gain. Brightness loss of the hand-sheets treated by the new compound is 10.2 ISO points and 5. 0 ISO points less than that of the blank sample and hand-sheets treated by VBL after 72 h UV accelerated irradiation, therefore it can be used as an effective yellowing inhibitior for lignin-containing paper products.关键词
化机浆/返黄抑制剂/光稳定剂/白度Key words
chemi-mechanical pulp/ yellowing inhibitor/ brightness stabilizer/ brightness分类
轻工纺织引用本文复制引用
张光华,徐海龙,郭锦鸽..新型返黄抑制剂的合成及性能研究[J].中国造纸,2012,31(11):25-29,5.基金项目
陕西省自然科学基金项目(项目编号:2009JM2010). （项目编号:2009JM2010）
