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锌掺杂对LiFePO4/C电化学性能的影响

左晶 王文静 王震 代爱萍

电池2012,Vol.42Issue(6):321-323,3.
电池2012,Vol.42Issue(6):321-323,3.

锌掺杂对LiFePO4/C电化学性能的影响

Effects of zinc doping on the electrochemical performance of LiFePO4/C

左晶 1王文静 1王震 1代爱萍1

作者信息

  • 1. 西安科技大学化学与化工学院,陕西西安710054
  • 折叠

摘要

Abstract

Carbon coated lithium iron phosphate (LiFePO4/C) and Zinc(Zn) doped LiFePO4/C were synthesized via co-precipitation method.The sample LiFe0.67Zn0.33PO4 had the olivine structure,the particle diameter was 0.04~47.90 μm.The doping of Zn reduced crystal size,increased the conductivity and Li+ diffusion rate. When the sample cycled 50 times with 0.2 C,0.5 C and 1.0 C in 2.0~4.2 V,its capacity retention rate was 95.2% , 82.9% and 79.9% ,respectively.

关键词

锌掺杂/磷酸铁锂(LiFePO4)/共沉淀法/电化学性能

Key words

Zn doping/lithium iron phosphate (LiFePO4)/ co-precipitation/ electrochemical performance

分类

信息技术与安全科学

引用本文复制引用

左晶,王文静,王震,代爱萍..锌掺杂对LiFePO4/C电化学性能的影响[J].电池,2012,42(6):321-323,3.

电池

OA北大核心CSCDCSTPCD

1001-1579

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