分析测试学报2012，Vol.31Issue(12)：1519-1524,6.DOI:10.3969/j.issn.1004-4957.2012.12.008
壬基酚表面印迹聚合物微球的合成及分子识别特性
Synthesis of Nonylphenol Surface Imprinted Polymer Microspheres and Their Molecule Recognition Characteristics
摘要
Abstract
By using surface molecular imprinting technique, a molecularly imprinted polymer(MIPs) for nonylphenol (NP) was synthesized on the surface of silica microparticles(SiMPs) with NP as template molecule, 2-methacrylic acid(MAA) as functional monomer and vinyltrimethoxysilane( VTFS) as grafting agent. The homogeneous dispersion of microspheres and larger specific surface area of the SMIP were observed by means of scanning electron microscopy (SEM) and BET adsorption apparatus. The characteritic of chemical structures in the modification procedure of MIP was studied by fourier transform infrared spectroscopy( FTTR) , and the adsorption property between the template molecule and functional polymer was evaluated by equilibrium adsorption method. The results indicated that the maximum adsorbing capacity of SMIP to NP was 184. 6 mg/g. In addition, the adsorption capacity of SMIP to NP was higher than those of its structural analogues, e. g. p-octylphenol and bisphenol A, indicating that SMIP has a good recogntion capacity to NP.关键词
表面分子印迹技术/壬基酚/二氧化硅微粒/聚合物微球/分子识别Key words
surface molecular imprinting technique/ nonylphenol/ silica microparticles/ polymer microsphere/ molecule recognition分类
化学化工引用本文复制引用
张进,牛延慧,王超英..壬基酚表面印迹聚合物微球的合成及分子识别特性[J].分析测试学报,2012,31(12):1519-1524,6.基金项目
贵州省教育厅自然科学基金资助项目(2010054) （2010054）
贵州省科学技术基金资助项目(J20112078) （J20112078）
贵州省生物学重点支持学科建设资助项目(2011231) （2011231）
