纺织高校基础科学学报2012，Vol.25Issue(4)：498-501,519,5.
钐-对苯二甲酸二元纳米配合物的合成及光学性能
Synthesis and optical properties of binary complex of samarium with terephthalic acid
摘要
Abstract
The nano complex Sm(l, 4-Hbdc) · 2H2O of SmCl3 · 6H2O with terephthalic acid was synthesized in ethanol water which was composed of 1:1 (V/V). The composition, optical properties, morphology and size of the nano complex were analyzed and characterized by EA,FTIR,DSC-TGA,UV-Vis, FS and TEM, respectively. The results showed that the oxygen atoms of carboxyl group from terephthalic acid is coordinated with Sm3+ ions in the nano complex,and it has some fluorescence property. And the size of the nano complex particles is between 3. 8nm and 68. 9nm,and each particle is the layered structure,the interlayer spacing of them is about 26. 3nm.关键词
钐二元配合物/对苯二甲酸/合成/光学性能Key words
binary complex of samarium/terephthalic acidjsynthesis/ optical properties分类
化学化工引用本文复制引用
朱文庆,王金平,苏飞飞..钐-对苯二甲酸二元纳米配合物的合成及光学性能[J].纺织高校基础科学学报,2012,25(4):498-501,519,5.基金项目
陕西省科技攻关项目(2011K07-23) （2011K07-23）
陕西省教育厅专项科研计划项目(11JK0566) （11JK0566）
西安工程大学博士基金项目(BS1010) （BS1010）
