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不同条件下碳酸羟基磷灰石的合成及吸附性能研究

张爱娟 王卫伟 李成峰

硅酸盐通报2012,Vol.31Issue(6):1371-1375,5.
硅酸盐通报2012,Vol.31Issue(6):1371-1375,5.

不同条件下碳酸羟基磷灰石的合成及吸附性能研究

Study on Synthesis of Carbonated Hydroxyapatite under Different Conditions and Its Adsorption Property

张爱娟 1王卫伟 1李成峰1

作者信息

  • 1. 山东理工大学材料科学与工程学院,淄博255049
  • 折叠

摘要

Abstract

Using ions coprecipitation method, four kinds of carbonated hydroxyapatites ( CHA ) were synthesized by changing addition way and order of CO2-3 . The phase composition, chemical composition, micromorphology of obtained CHA were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, Scanning electron microscope, respectively. The results showed that four kinds of samples were carbonated hydroxyapatite partially substituted (including Type-A and Type-B ) by CO2-3~. The substitution amount, which reflects the degree of lattice distortion and has some influence on adsorption performance as a result, was sample 2 > sample 1 > sample 3 > sample 4 from large to small order. In order to compare the adsorbability of four samples, the experiments on adsorption of Cu2+ in an aqueous solution were done and the results showed that the removal rate of Cu2+ of four samples are far above that of standard HA, with sample 2 leading the way and reaching 99. 42% .

关键词

羟基磷灰石/碳酸羟基磷灰石/A/B型取代/Cu2+吸附

Key words

hydroxyapatite/ carbonated hydroxyapatite/ type-A and type-B substitution/ Cu2+ adsorption

分类

化学化工

引用本文复制引用

张爱娟,王卫伟,李成峰..不同条件下碳酸羟基磷灰石的合成及吸附性能研究[J].硅酸盐通报,2012,31(6):1371-1375,5.

基金项目

山东省高等学校科技计划项目(J11LD52) (J11LD52)

硅酸盐通报

OA北大核心CSCDCSTPCD

1001-1625

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