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磷酸钾镁水泥水化体系的微结构演化

周序洋 杨建明 王进

硅酸盐通报2012,Vol.31Issue(6):1438-1444,7.
硅酸盐通报2012,Vol.31Issue(6):1438-1444,7.

磷酸钾镁水泥水化体系的微结构演化

Microstructure Evolution of Magnesium-potassium Phosphate Cement Paste

周序洋 1杨建明 2王进3

作者信息

  • 1. 江苏城市职业学院,南京210019
  • 2. 南京建工集团有限公司,南京200012
  • 3. 盐城工学院江苏省生态环境材料重点建设实验室,盐城224051
  • 折叠

摘要

Abstract

In order to study microstructure evolution of magnesium-potassium phosphate cement paste, its hydration heat and compressive strength development of magnesium-potassium phosphate cement (MKPC) paste were tested, and its phase composition and microstructure were analyzed. The results show that the hydration of MKPC paste is rapid and releases large amounts of hydration heat at the beginning. The hydration reaction of MKPC paste almost completes in first 3 d, and which generates main hydrates magnesium potassium phosphate hexahydrate (MgKP04·6H2O-MKP) and some phosphate hydrates with low-bound water. The hydrates crystals have many defects and poor stability due to quick hydration and produce large internal stress in growing. The phosphate hydrates with low-bound water gradually absorb water in air and transform into MKP. The factors above result in deterioration of the structure of hardened MKPC paste, namely more cracks and defects in the section of hardened MKPC paste with curing age, and that lead to quick development of compressive strength of MKPC paste in first 3 d, the retraction of compressive strength later and gradual recovery of compressive strength further.

关键词

磷酸钾镁水泥(MKPC)/水化热/抗压强度/微结构演化

Key words

potassium and magnesium phosphate cement ( MKPC ) / hydration heat/ compressive strength/microstructure

分类

建筑与水利

引用本文复制引用

周序洋,杨建明,王进..磷酸钾镁水泥水化体系的微结构演化[J].硅酸盐通报,2012,31(6):1438-1444,7.

基金项目

建设部科研开发项目(2010-K4-38),(2011-K4-23) (2010-K4-38)

硅酸盐通报

OA北大核心CSCDCSTPCD

1001-1625

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