硅酸盐学报2012，Vol.40Issue(12)：1779-1785,7.
六亚甲基四胺辅助微波水热法合成γ-MnS微晶球及其光学性能
Hexamethylene Tetramine-Assisted Microwave Hydrothermal Synthesis and Optical Properties of Spherical γ-MnS Crystallites
摘要
Abstract
Spherical γ-MnS crystallites were synthesized with manganese chloride and thioacetamide as source materials and hexa- methylene tetramine (HMTA) as an additive by a microwave hydrothermal process. The influence of the HMTA amount on the phase structure and morphology of the crystallites was investigated by X-ray diffraction and field emission scanning electron microscopy, respectively. The results show that the morphology of the products changes from hexagonal columns to hexagonal flakes and self-assembled into spherical crystallites when adding the HMTA of 5 mmol. The surface of the self-assembled spheres becomes smoother, and the corresponding particle size decreases and the particle size distribution becomes narrower when the amount of HMTA increases. The UV-Visible spectrum analysis indicates that the hexagonal flakes self-assembled spherical γ-MnS crystallites have an intensive absorption peak in the ultraviolet spectrum between 300-400 nm. Also, the absorption peak becomes more and more intensive when the amount of the HMTA increases, exhibiting a red shift that may have a potential application prospect in photoelectric areas.关键词
微波水热法/γ-硫化锰微晶球/六亚甲基四胺Key words
microwave hydrothermal method/spherical y-manganese sulfide crystallites/hexamethylene tetramine分类
数理科学引用本文复制引用
辛宇,黄剑锋,曹丽云,刘佳,吴建鹏..六亚甲基四胺辅助微波水热法合成γ-MnS微晶球及其光学性能[J].硅酸盐学报,2012,40(12):1779-1785,7.基金项目
国家自然科学基金 （）
陕西省国际科技合作重点项目2011KW-11） （）
陕西省自然科学基金 （）
陕西省教育厅自然科学专项基金 （）
陕西科技大学研究生创新基金资助项目. （）
