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活性碳纤维对水中喹啉的吸附性能

张培 张小平 方益民 兰永辉

化工进展2013,Vol.32Issue(1):209-213,5.
化工进展2013,Vol.32Issue(1):209-213,5.DOI:10.3969/j.issn.1000-6613.2013.01.036

活性碳纤维对水中喹啉的吸附性能

Adsorption characteristics of quinoline on activated carbon fiber

张培 1张小平 1方益民 2兰永辉3

作者信息

  • 1. 华南理工大学环境科学与工程学院,工业聚集区污染控制与生态修复教育部重点实验室,广东广州510006
  • 2. 广东省废物管理中心,广东广州510308
  • 3. 东江环保股份有限公司,广东深圳518057
  • 折叠

摘要

Abstract

The static adsorption of quinoline on activated carbon fiber (ACF) was studied. The factors effecting adsorption efficiency and behaviors such as time, quinoline does, temperature, pH and organic compound were investigated. The results show that quinoline adsorption capacity on ACF was up to 210 mg/g at higher concentration and adsorption efficiency decreased with an increase of temperature. It was found that ACF had good adsorption properties when pH<7. The presence of organic substances inhibits the sorption efficiency. The adsorption isotherms conform to Langmuir adsorption isotherm and the adsorption process fits a pseudo-second-order model. The sorption parameters Δ/f° and ΔG° were both negative, so the adsorption is spontaneous and exothermic. Scientific basis is offered for environment function material ACF using in industrial production. Based on the experimental results, dynamic adsorption experiment and treatment of coke plant wastewater is necessary. In addition, the problem of the respect such as high cost and desorption regeneration of ACF remain to be further studied.

关键词

活性碳纤维/喹啉/吸附/动力学/热力学

Key words

activated carbon fiber/quinoline/adsorption/kinetics/thermodynamics

分类

资源环境

引用本文复制引用

张培,张小平,方益民,兰永辉..活性碳纤维对水中喹啉的吸附性能[J].化工进展,2013,32(1):209-213,5.

基金项目

广东省教育部产学研结合项目(2011B090400636)及亚热带建筑科学国家重点实验室开放课题(2013KB28). (2011B090400636)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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