化学工程2012，Vol.40Issue(12)：57-59,74,4.DOI:10.3969/j.issn.1005-9954.2012.12.014
液液萃取分离乙酸甲酯与甲醇水溶液的模拟计算
Modeling calculation of liquid-liquid extraction of methyl acetate and methanol aqueous solution
曹宇锋 1顾正桂 2施磊 1李建华 1苏广均1
作者信息
- 1. 南通大学化学化工学院,江苏南通226019
- 2. 南京师范大学江苏省萃取分离工程技术研究中心,江苏南京210097
- 折叠
摘要
Abstract
The technological process of cross-extractive separation of methyl acetate and methanol aqueous solution was designed. Glycerol and water were selected as the best solvents of extractive separation. Activity coefficients were calculated by UNIQUAC equation. The infinite dilution activity coefficient of methanol in glycerol was measured by the gas chromatogram apparatus, and the parameters of UNIQUAC equation were calculated by the single parameter method. The cross-extractive separation was simulated by phase separation coefficients and material balance equation. The simulation program diagram was established. The optimization results were compared with the experimental data, and the relative error was only 0. 01%. The results show that the mass fraction and the yield of methyl acetate reach 99. 7% and 97. 0% respectively when theoretical stage is 3. The simulation results can provide theoretical basis for further research.关键词
乙酸甲酯/甲醇/水/甘油/液液萃取Key words
methyl acetate/ methanol/ water/ glycerol/ liquid-liquid extraction分类
化学化工引用本文复制引用
曹宇锋,顾正桂,施磊,李建华,苏广均..液液萃取分离乙酸甲酯与甲醇水溶液的模拟计算[J].化学工程,2012,40(12):57-59,74,4.
