中国塑料Issue(12):40-44,5.
PE—LLD/纳米Al2O3复合材料非等温结晶动力学研究
Study on Non-isothermal Crystallization Kinetics of PE-LLD/Nano-Al2 O3 Composites
何小芳 1张崇 1王李波 1戴亚辉 1曹新鑫1
作者信息
- 1. 河南理工大学材料科学与工程学院,河南焦作454000
- 折叠
摘要
Abstract
Non-isothermal crystallization behavior of linear low density polyethylene (PE-LLD)/ nano-Al2O3 composites was investigated using differential scanning calorimetry. The nonisothermal crystallization kinetics was analyzed with Avrami and Mo methods. Kissinger method was used to estimate the activation energy for non-isothermal crystallization. When the content of nano-Al2O3 was between 5 % and 10 %, the heterogeneous nucleation in the crystallization process of PE-LLD was sufficient, the crystallization onset temperature, peak temperature, and crystallization rate increased only slightly. The addition of nano-Al2 O3 decreased the activation energy of PE-LLD.关键词
线形低密度聚乙烯/纳米氧化铝/复合材料/非等温结晶动力学Key words
linear tow density polyethylene/nano aluminium oxide/composite/non-isothermal crystallization kinetics分类
化学化工引用本文复制引用
何小芳,张崇,王李波,戴亚辉,曹新鑫..PE—LLD/纳米Al2O3复合材料非等温结晶动力学研究[J].中国塑料,2012,(12):40-44,5.