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PE—LLD/纳米Al2O3复合材料非等温结晶动力学研究

何小芳 张崇 王李波 戴亚辉 曹新鑫

中国塑料Issue(12):40-44,5.
中国塑料Issue(12):40-44,5.

PE—LLD/纳米Al2O3复合材料非等温结晶动力学研究

Study on Non-isothermal Crystallization Kinetics of PE-LLD/Nano-Al2 O3 Composites

何小芳 1张崇 1王李波 1戴亚辉 1曹新鑫1

作者信息

  • 1. 河南理工大学材料科学与工程学院,河南焦作454000
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摘要

Abstract

Non-isothermal crystallization behavior of linear low density polyethylene (PE-LLD)/ nano-Al2O3 composites was investigated using differential scanning calorimetry. The nonisothermal crystallization kinetics was analyzed with Avrami and Mo methods. Kissinger method was used to estimate the activation energy for non-isothermal crystallization. When the content of nano-Al2O3 was between 5 % and 10 %, the heterogeneous nucleation in the crystallization process of PE-LLD was sufficient, the crystallization onset temperature, peak temperature, and crystallization rate increased only slightly. The addition of nano-Al2 O3 decreased the activation energy of PE-LLD.

关键词

线形低密度聚乙烯/纳米氧化铝/复合材料/非等温结晶动力学

Key words

linear tow density polyethylene/nano aluminium oxide/composite/non-isothermal crystallization kinetics

分类

化学化工

引用本文复制引用

何小芳,张崇,王李波,戴亚辉,曹新鑫..PE—LLD/纳米Al2O3复合材料非等温结晶动力学研究[J].中国塑料,2012,(12):40-44,5.

中国塑料

OA北大核心CSCDCSTPCD

1001-9278

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