中国造纸学报2012，Vol.27Issue(4)：43-49,7.
黑液高温气化合成混合醇的操作条件分析
Operation Conditions Analysis of Higher Alcohol Synthesis via Syngas from High Temperature Gasification of Black Liquor
摘要
Abstract
The objective of the paper is to optimize the operation conditions of higher alcohol synthesis via raw syngas from high temperature gasification of black liquor. The process of CO2 removal from syngas is simulated by commercial software Aspen plus. The variations of H2S content, absorbent consumption and heat load for absorbent regeneration with CO2 content in clean singes (reactant) are analyzed. The synthesis process is analyzed based on the model of a fixed bed reactor and K/MoS2 catalyst. Products distributions and yields are predicted. The influence of operation conditions, including CO2 content in reactant, catalyst loading, reaction temperature and pressure on CO conversion ratio, selectivities of alcohol, hydrocarbon, CO2 and ester, mass content of C2 + alcohol and space time yield are studied by sensitive studies. Analysis results show that the optimum operation conditions of the reactor are: temperature 310～330℃ , pressure 9～11 MPa, catalyst loading ratio 20 ～30 g·h/mol and CO2 content 1. 6% .关键词
黑液气化/混合醇合成/反应动力学模型/操作条件Key words
black liquor gasification/ higher alcohols synthesis/ kinetic modelling/ operation conditions分类
化学化工引用本文复制引用
王逊,高峻,孙振丽..黑液高温气化合成混合醇的操作条件分析[J].中国造纸学报,2012,27(4):43-49,7.基金项目
国家自然科学基金项目(51176186). （51176186）
