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CdSe/TiO2复合薄膜的制备及光电性能研究

薛晋波 李雪方 梁伟 王红霞

材料工程Issue(1):21-24,4.
材料工程Issue(1):21-24,4.DOI:10.3969/j.issn.1001-4381.2013.01.005

CdSe/TiO2复合薄膜的制备及光电性能研究

Preparation and Characterization of Nano-heterojunction CdSe/TiO2 Film

薛晋波 1李雪方 2梁伟 3王红霞1

作者信息

  • 1. 太原理工大学材料科学与工程学院,太原030024
  • 2. 太原理工大学山西省新材料工程技术研究中心,太原030024
  • 3. 太原理工大学新材料界面科学与工程教育部重点实验室,太原030024
  • 折叠

摘要

Abstract

CdSe thin films were fabricated on ITO glass substrate and TiO2 nanotube arrays by electrochemical method in a three-electrode system in electrolyte containing SeO2, CdCl2 o 5/2H2O and H2SO4 at room temperature. The crystalline structure and morphology of the composite films prepared under different deposited potentials ( - 0.6,-0. 7,-0.8,-0. 9V, vs SCE) were investigated, and the optical properties of the composite films were measured. The results show that the prepared CdSe nanoparticles are agglomerated inhomogeneously. The optical absorption and photoelectric current of composite films are enhanced with the deposited potential increasing. The film deposited under - 0. 8V exhibits the maximum photoelectric current, but it is easy to peel from the substrate. According to the fastness and photocurrent response of the composite film, the suitable deposition voltage is around -0. 7V for obtaining the optimum film.

关键词

电化学沉积/TiO2纳米管/沉积电压/CdSe纳米晶薄膜

Key words

electrochemical deposition /TiO2 nanotube [deposited voltage/ CdSe nanoparticle

分类

信息技术与安全科学

引用本文复制引用

薛晋波,李雪方,梁伟,王红霞..CdSe/TiO2复合薄膜的制备及光电性能研究[J].材料工程,2013,(1):21-24,4.

基金项目

国家自然科学基金资助项目(51175363) (51175363)

山西省科技攻关基金(20090321071) (20090321071)

太原理工大学校青年基金(K201013) (K201013)

材料工程

OA北大核心CSCDCSTPCD

1001-4381

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