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废铅蓄电池火法冶炼的联合脱硫除铅工艺研究

李宝宁 许绿丝 郭小燕 程辛

电源技术2013,Vol.37Issue(1):93-96,4.
电源技术2013,Vol.37Issue(1):93-96,4.

废铅蓄电池火法冶炼的联合脱硫除铅工艺研究

Research on integrated technique of desulfurization and lead-removal in process of pyrometallurgy of spent lead battery

李宝宁 1许绿丝 1郭小燕 1程辛1

作者信息

  • 1. 华侨大学化工工程学院,福建厦门361021
  • 折叠

摘要

Abstract

Integrated technique of desulfurization and lead-removal were studied for treating lead mud and by-product from the process of pyrometallurgy of spent lead battery in the paper. The methods that the NaCO3 used in lead mud desulfuration, CaO used in fixing sulfur of liquid, and NaCI-FeCI3 system used in removed lead of fix-sulfur solid were adopted. The results show that the fix sulfur rate is 77.47%, and lead leaching rate is 99.14%.The integrated technique has a much better effect in comparison with separate technique. NaOH in the liquid after fixing sulfur can cut the amount of NaCO3, and can be recycled as water for fragmentation and gas desulfurizer. The lead leaching rate of lead-removal liquid is as much as 31%. In that case, the less NaCI-FeCI3, is needed in lead-removal. Dealing with a ton spent lead battery, SO2 can be reduced by 3.532 kg, and economic benefit was 374.376 yuan can be gained. Compared with separate technique, this technique can conserve energy, cut emission, and reduce the pollution with remarkable economic and environmental benefits.

关键词

废铅蓄电池/脱硫/除铅/节能减排

Key words

spent lead battery/ desulfurization/ lead removal/ energy saving and emission reduction

分类

信息技术与安全科学

引用本文复制引用

李宝宁,许绿丝,郭小燕,程辛..废铅蓄电池火法冶炼的联合脱硫除铅工艺研究[J].电源技术,2013,37(1):93-96,4.

基金项目

国家自然科学基金(51178195) (51178195)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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