分析化学2013，Vol.41Issue(1)：119-122,4.DOI:10.3724/SP.J.1096.2013.20599
气相色谱-质谱法测定木材及木制品中的有机锡化合物
Determination of Organotin Compounds in Timber and Wood Products by GC-MS
摘要
Abstract
The gas chromatography-mass spectrometric (GC-MS) method was developed for the determination of 4 organotin compounds in timber and wood products. According to the preservative retention capacity, effective concentration and timber density, the analog samples were made of pine wood and plywood for experimental condition optimization. The analytes were extracted in ethanol and derivatised with NaBEt4(2% ) at pH 5 with acetate buffer solution by ultrasonic bathing. The species of monobutyltin (MBT) , dibutyltin (DBT) , tributyltin(TBT) and triphenyltin(TPhT) are extracted with hexane and then detected simultaneously by GC-MS . The method has a good reproducibility and recovery with the linearity in the ranges of 0. 1 — 20 mg/L. The average recoveries were in the range of 83. 6% and 103. 2% with the relative standard deviations of less than 9.8%.关键词
有机锡/气相色谱-质谱/木材及木制品Key words
Organotin/ Gas chromatography-mass spectrometry/ Timber and wood products引用本文复制引用
戚佳琳,杨桂朋,王兆锟,牛增元..气相色谱-质谱法测定木材及木制品中的有机锡化合物[J].分析化学,2013,41(1):119-122,4.基金项目
本文系质检公益性行业科研专项课题(No.10-66)资助 （No.10-66）
