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卟啉单体和卟啉二聚体的光限幅性质

郑文琦 单凝 法焕宝 石莹岩

吉林大学学报(理学版)2013,Vol.51Issue(1):135-139,5.
吉林大学学报(理学版)2013,Vol.51Issue(1):135-139,5.

卟啉单体和卟啉二聚体的光限幅性质

Optical Limiting Properties of Porphyrin Monomers and Dimers

郑文琦 1单凝 2法焕宝 3石莹岩1

作者信息

  • 1. 吉林建筑工程学院基础科学部,长春130118
  • 2. 吉林大学学报(理学版)编辑部,长春130012
  • 3. 重庆大学化学化工学院,重庆400044
  • 折叠

摘要

Abstract

The authors synthesized three porphyrin monomers with different substituents and three porphyrin dimers with different bridge-linked reagents according to Alder method. The optical limiting properties of the porphyrins were studied via Z-scan and optical limiting properties, and compared with those of other porphyrin molecules under the similar experimental conditions. The Z-scan curves of all the porphyrin samples were similar to each other. The Z-scan curves of all the porphyrin samples showed the characteristics of reverse saturation absorption. Porphyrin 4 had the best optical limiting properties, and the lowest normalized transmittance of porphyrin 4 was 7%.

关键词

卟啉/单体/二聚体/Z-扫描曲线/反饱和吸收/光限幅性质

Key words

porphyrin/ monomer/ dimer/ Z-scan curves/ reverse saturation absorption/ optical limiting property

分类

化学化工

引用本文复制引用

郑文琦,单凝,法焕宝,石莹岩..卟啉单体和卟啉二聚体的光限幅性质[J].吉林大学学报(理学版),2013,51(1):135-139,5.

基金项目

吉林省教育厅"十一五"科学技术项目(批准号:2009417)和吉林建筑工程学院博士科研启动基金(批准号:861004). (批准号:2009417)

吉林大学学报(理学版)

OA北大核心CSCDCSTPCD

1671-5489

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