煤炭转化2013,Vol.36Issue(1):19-23,5.
稻壳与褐煤共热解过程的TG-FTIR分析
TG-FTIR ANALYSIS OF CO-PYROLYSIS OF RICE HUSK AND LIGNITE
摘要
Abstract
TG-FTIR was used to analyze the co-pyrolysis process of rice husk and lignite. It was found that the co-pyrolysis mass lost were larger than mono-pyrolysis, especially when mixed ratio of rice husk and lignite was 2 : 8. The co-pyrolysis products component changed, with CO2 increased, CH4 decreased, CO increased a little, while other organic compounds like phenols, carbonyl compounds, and aromatic compound all decreased a little. The mechanism of co-pyrolysis process was investigated. The metallic oxide in biomass could restrain the process of coal bond into coke so biomass and coal co-pyrolysis process took place the synergistic effect; thus it contributes to the further decomposition of coal. In addition, the biomass generates H2 earlier than coal during co-pyrolysis, and the condensation reaction of coal at high temperature is inhibited because of H2; so the prolysis of coal is promoted.关键词
稻壳/褐煤/共热解/TG-FTIR/协同作用Key words
rice husk/lignite/co-pyrolysis/TG-FTIR/synergistic effect分类
化学化工引用本文复制引用
赵淑蘅,蒋剑春,孙云娟,胡亿明,徐凡..稻壳与褐煤共热解过程的TG-FTIR分析[J].煤炭转化,2013,36(1):19-23,5.基金项目
国家自然科学基金资助项目(31100521)、江苏省生物质能源与材料重点实验室开放基金资助项目(JSBEM201208)和林业公益性行业专项项目(200904062). (31100521)