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稻壳与褐煤共热解过程的TG-FTIR分析

赵淑蘅 蒋剑春 孙云娟 胡亿明 徐凡

煤炭转化2013,Vol.36Issue(1):19-23,5.
煤炭转化2013,Vol.36Issue(1):19-23,5.

稻壳与褐煤共热解过程的TG-FTIR分析

TG-FTIR ANALYSIS OF CO-PYROLYSIS OF RICE HUSK AND LIGNITE

赵淑蘅 1蒋剑春 1孙云娟 1胡亿明 1徐凡1

作者信息

  • 1. 中国林业科学研究院林产化学工业研究所,江苏省生物质能源与材料重点实验室,国家林业局林产化学工程重点开放性实验室,生物质化学利用国家工程实验室,210042南京
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摘要

Abstract

TG-FTIR was used to analyze the co-pyrolysis process of rice husk and lignite. It was found that the co-pyrolysis mass lost were larger than mono-pyrolysis, especially when mixed ratio of rice husk and lignite was 2 : 8. The co-pyrolysis products component changed, with CO2 increased, CH4 decreased, CO increased a little, while other organic compounds like phenols, carbonyl compounds, and aromatic compound all decreased a little. The mechanism of co-pyrolysis process was investigated. The metallic oxide in biomass could restrain the process of coal bond into coke so biomass and coal co-pyrolysis process took place the synergistic effect; thus it contributes to the further decomposition of coal. In addition, the biomass generates H2 earlier than coal during co-pyrolysis, and the condensation reaction of coal at high temperature is inhibited because of H2; so the prolysis of coal is promoted.

关键词

稻壳/褐煤/共热解/TG-FTIR/协同作用

Key words

rice husk/lignite/co-pyrolysis/TG-FTIR/synergistic effect

分类

化学化工

引用本文复制引用

赵淑蘅,蒋剑春,孙云娟,胡亿明,徐凡..稻壳与褐煤共热解过程的TG-FTIR分析[J].煤炭转化,2013,36(1):19-23,5.

基金项目

国家自然科学基金资助项目(31100521)、江苏省生物质能源与材料重点实验室开放基金资助项目(JSBEM201208)和林业公益性行业专项项目(200904062). (31100521)

煤炭转化

OA北大核心CSCDCSTPCD

1004-4248

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