皮革科学与工程2013，Vol.23Issue(1)：48-51,4.
羧基化聚甲基三氟丙基硅氧烷的合成及应用
Synthesis and Application of Carboxylated Polymethyltrifluoropropylsiloxane
摘要
Abstract
A novel carboxylated polymethyltrifluoropropylsiloxane ( FCAS) was synthesized through the reaction of maleic anhydride and pendant aminopropyl groups-containing polymethyltrifluoropropylsiloxane ( FASO) , which was firstly prepared via copolymerization of hexamethyldisiloxane (MM) , octamethyl cyclotetrasiloxane (D4) , 1,3,5 - trimethyltris (3,3,3 - trifluoropyropyl) cyclotrisiloxane ( D3F ) and γ - aminopropylmethyldimethoxysilane ( KH551 ) under strong alkaline catalyst. Then FCAS was emulsified to treat the wet -blue goat. Infrared spectrum (IR) , proton nuclear magnetic resonance (1H NMR) , Transmission Electron Microscope (TEM) , nano particle size, ζ potential analyzer and static contact angle analyzer were utilized to characterize the structure of target product, particle morphology and average size, ζ potential as well as hydrophobicity such as water contact angle on the grain side of treated crust leather. Results showed that final product had due structure. FCAS latices particles presented regular sphere with narrow particle distribution and an average diameter of 78 ran and possessed smooth surface as well as ζ potential of - 37. 53 mV. The treated crust leather by 1. 92% FCAS active ingredients based on the weight of wet - blue goat had preferable hydrophobicity and water contact angle on its grain side attained 144. 5°.关键词
羧基硅乳/聚甲基三氟丙基硅氧烷/皮革防水Key words
carboxylated polysiloxane emulsion/ polymethyltrifluoropropylsiloxane/ leather repellency分类
轻工纺织引用本文复制引用
郝丽芬,安秋凤,丁宇,许伟..羧基化聚甲基三氟丙基硅氧烷的合成及应用[J].皮革科学与工程,2013,23(1):48-51,4.基金项目
陕西省自然科学研究基金项目(2012JM6013) （2012JM6013）
陕西科技大学自然科学基金项目(ZX11-18) （ZX11-18）
