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压力对加压煤气化过程中氮释放的影响

刘安琪 赵增立 武宏香 王小波 郑安庆 李海滨 张尚武 黄戒介

燃料化学学报2013,Vol.41Issue(1):14-19,6.
燃料化学学报2013,Vol.41Issue(1):14-19,6.

压力对加压煤气化过程中氮释放的影响

Influence of pressure on the release of nitrogen during pressurized gasification of coal

刘安琪 1赵增立 1武宏香 1王小波 1郑安庆 1李海滨 1张尚武 2黄戒介2

作者信息

  • 1. 中国科学院广州能源研究所中国科学院可再生能源与天然气水合物重点实验室,广东广州510640
  • 2. 中国科学院山西煤炭化学研究所山西省粉煤气化工程研究中心,山西太原030001
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摘要

Abstract

A comprehensive knowledge of the release characteristics of inorganic compounds is required by the designing of gas scrubbing and hot gas cleaning technology. The principal objective of this work was to examine the influence of pressure on the release of nitrogen during pressurized coal gasification in a pilot-scale pressurized ash agglomerating fluidized bed facility with 800 mm i. d. . Jincheng anthracite was gasified at gage pressures of 0.6, 1.0, 1.5 and 2.0 MPa with steam/O2(3/l, volume ratio) at 1 000 ℃. The analysis of nitrogen content and form in hot gas and solid by-product was carried out. The quantitative analysis results show that most of nitrogen is transferred into gas phase, which is slightly changed after 1. 0 MPa coupled with an enrichment of nitrogen in solid phase with the increase in pressure. The discussion on the mechanism of nitrogen release at pressure was carried out by contrast analysis of nitrogen form in the coal and bottom ash at microcosmic level.

关键词

煤气化/压力/

Key words

coal gasification/pressure/nitrogen

分类

化学化工

引用本文复制引用

刘安琪,赵增立,武宏香,王小波,郑安庆,李海滨,张尚武,黄戒介..压力对加压煤气化过程中氮释放的影响[J].燃料化学学报,2013,41(1):14-19,6.

基金项目

国家高技术研究发展计划(863计划,2008AA050302-06) (863计划,2008AA050302-06)

中国科学院广州能源所所长基金(o807pk1001). (o807pk1001)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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