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异山梨醇-马来酸酐聚酯改性PET的研究

吴爽 王鑫 陈平

石油化工高等学校学报2013,Vol.26Issue(1):6-10,5.
石油化工高等学校学报2013,Vol.26Issue(1):6-10,5.DOI:10.3969/j.issn.1006-396X.2013.01.002

异山梨醇-马来酸酐聚酯改性PET的研究

PET Modified with Copolyester of Isosorbide/Maleic Anhydride

吴爽 1王鑫 2陈平1

作者信息

  • 1. 辽宁石油化工大学化学与材料科学学院,辽宁抚顺113001
  • 2. 抚顺石油化工研究院,辽宁抚顺113001
  • 折叠

摘要

Abstract

PET-c-IS-MA was prepared from PET which modified by copolyester of isosorbide/maleic anhydride through reactive extrusion. PET-c-IS-MA had the similar θg and θm as that of PET and a single phase structure from thermal gravity analysis. PET-c-IS-MA with the maximum amount of 30% IS-MA could remain the thermal properties of PET. PET-c-IS-MA shows higher crystal property than PET for the presence of θc from 125℃ to 130℃ , and hence improved the process characteristics by changing the crystal degree of PET-c-IS-MA. Moreover, PET-c-IS-MA possessed higher water resistance, better stability in acid or alkaline medium and biodegradation.

关键词

异山梨醇/PET/改性/降解性

Key words

Isosorbide/ PET/ Modified/ Biodegradation

分类

能源科技

引用本文复制引用

吴爽,王鑫,陈平..异山梨醇-马来酸酐聚酯改性PET的研究[J].石油化工高等学校学报,2013,26(1):6-10,5.

基金项目

国家自然科学基金项目(20974042). (20974042)

石油化工高等学校学报

OACSTPCD

1006-396X

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