无机材料学报2012，Vol.27Issue(12)：1271-1276,6.DOI:10.3724/SP.J.1077.2012.12135
磺化石墨烯及其导电炭薄膜的制备与性能
Synthesis and Characterization of Sulfonated Graphene and Conducting Films
摘要
Abstract
Graphite oxide (GO) was prepared from graphite by Hummers liquid oxidation method and the sulfonated graphene (S-GNS) was then prepared by pre-reduction, sulfonation and post-reduction. Glucose was also used to reduce the agglomeration among the graphene layers. The as-prepared sulfonated graphene was characterized by Fourier transform infrared spectroscope (FT-IR), X-ray photoelectron spectroscope (XPS), Thermo-gravimetric analysis (TG), X-ray diffraction (XRD), Scanning electron microscope (SEM), Transmission electron microscope (TEM) and Atomic force microscope (AFM), respectively. The experimental results indicate that the graphene of the p-phenyl-SO3H groups is successfully grafted into graphite oxide, and graphite oxide is completely reduced to sulfonated graphene. The sulfonated graphene possesses high thermal stability, smooth surface and few defects, and the thickness of single layer graphene is approximately 1.2 nm. Water solubility and dispersion results show that the sulfonated graphene can be dispersed into water with good water solubility. In addition, the BET specific surface area and the electrical conductivity of the sulfonated graphene film are up to 806.4 m2/g and 1150 S/m, respectively.关键词
石墨烯/氧化石墨/磺化/氧化还原Key words
graphene/ graphite oxide/ sulfonation/ oxidation-reduction分类
化学化工引用本文复制引用
袁文辉,顾叶剑,李保庆,李莉..磺化石墨烯及其导电炭薄膜的制备与性能[J].无机材料学报,2012,27(12):1271-1276,6.基金项目
国家自然科学基金(20976057) （20976057）
