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负载CeO2的改性活性炭吸附脱硫性能研究

陈凤翔 熊麟 刘欣 程远佳

西安石油大学学报(自然科学版)2013,Vol.28Issue(1):89-93,5.
西安石油大学学报(自然科学版)2013,Vol.28Issue(1):89-93,5.

负载CeO2的改性活性炭吸附脱硫性能研究

Study on absorptive desulfurization performance of modified activated carbon loading CeO2

陈凤翔 1熊麟 2刘欣 1程远佳1

作者信息

  • 1. 武汉纺织大学纺织科学与工程学院,湖北武汉 430073
  • 2. 长江大学化学与环境工程学院,湖北荆州 434023
  • 折叠

摘要

Abstract

Ceria-loaded carbon was prepared by dipping-calcining method,and its absorption capacity to dibenzothiophene (DBT) in model fuels was tested. The adsorbents and original materials were also characterized by means of nitrogen adsorption,FTIR,and Boe-hm titration. The results show that the optimal ceria loading capability of activated carbon is 1.29 % ( mass fraction), the maximum adsorption capacity of the sample to DBT was calculated according to Langmuir model,and it is nearly 139.2% of the adsorption capacity . of the original activated carbon. The texture and surface chemistry analysis of the modified activated carbon show that the improvement of its absorption capacity is mainly due to the increase of acidic sites on the adsorbent surface and the interaction between cerium ion and dibenzothiophene.

关键词

吸附脱硫/改性/活性炭/CeO2

Key words

adsorptive desulfurization/ modified activated carbon/ CeO2 / dipping-calcining

分类

能源科技

引用本文复制引用

陈凤翔,熊麟,刘欣,程远佳..负载CeO2的改性活性炭吸附脱硫性能研究[J].西安石油大学学报(自然科学版),2013,28(1):89-93,5.

基金项目

国家自然科学基金(编号:51203124) (编号:51203124)

西安石油大学学报(自然科学版)

OA北大核心CSTPCD

1673-064X

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