应用化学2013，Vol.30Issue(1)：28-31,4.DOI:10.3724/SP.J.1095.2013.20072
Al2O3-SiO2催化环己胺氧化制备环己酮肟
Oxidation of Cyclohexylamine to Cyclohexanone Oxime Catalyzed by Al2O3-SiO2
摘要
Abstract
The oxidation of cydohexylamine catalyzed by Al2O3-SiO2 catalyst was carried out under mild conditions.The effects of solvent amount,catalyst amount,reaction time and reaction temperature on the reaction were investigated.Under the conditions of F( acetonitrile): V( cydohexylamine) =3:1,31.0% mass fraction of catalyst,reaction temperature of 75℃,and reaction time of 5 h,the conversion of cydohexylamine reaches up to 100% and the selectivity for cyclohexanone oxime is 83.6%.A reaction mechanism is proposed.关键词
环己胺/氧化/环己酮肟Key words
cydohexylamine/oxidation/cyclohexanone oxime分类
化学化工引用本文复制引用
高美香,罗东,毛丽秋,尹笃林..Al2O3-SiO2催化环己胺氧化制备环己酮肟[J].应用化学,2013,30(1):28-31,4.基金项目
国家自然科学基金资助项目(20976043) （20976043）
