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甲醛改性多壁碳纳米管吸附铀的性能研究

刘淑娟 李金英 罗明标 花榕 林海禄 马建国

原子能科学技术2013,Vol.47Issue(1):7-13,7.
原子能科学技术2013,Vol.47Issue(1):7-13,7.DOI:10.7538/yzk.2013.47.01.0007

甲醛改性多壁碳纳米管吸附铀的性能研究

Adsorption of Uranium With Multiwall Carbon Nanotubes Modified by Formaldehyde

刘淑娟 1李金英 2罗明标 2花榕 1林海禄 1马建国1

作者信息

  • 1. 东华理工大学核资源与环境省部共建国家重点实验室培育基地,江西南昌330013
  • 2. 中国原子能科学研究院放射化学研究所,北京102413
  • 折叠

摘要

Abstract

Purified multiwall carbon nanotubes (MWCNTs) were modified with formaldehyde and the dispersibility of MWCNTs was greatly improved after modification. The modified MWCNTs were used to study the adsorption of uranium from aqueous solution. pH, contact time, temperature, initial concentration of uranium and modified MWCNTs concentrations were investigated to estimate the adsorptive properties. The results show that uranium adsorption percentage strongly depends on the pH, initial concentration of uranium and modified MWCNTs content, and is slightly influenced by contact time, temperature and ionic strength. The adsorptivity increases over the range of pH = 2. 0-7. 0. The maximum adsorptivity is 46. 44 mg/g as the initial concentration of uranium reaches 50 μg/mL. The equilibrium data obey both Langmuir and Freundlich isotherms well, and the maximal theoretical adsorption capacity is 55. 87 mg/g for the modified MWCNTs.

关键词

改性多壁碳纳米管/吸附//吸附等温线

Key words

modified MWCNTs/ adsorption/ uranium/ adsorption isotherm

分类

化学化工

引用本文复制引用

刘淑娟,李金英,罗明标,花榕,林海禄,马建国..甲醛改性多壁碳纳米管吸附铀的性能研究[J].原子能科学技术,2013,47(1):7-13,7.

基金项目

江西省自然科学基金资助项目(2010GZH0012) (2010GZH0012)

东华理工大学核资源与环境重点实验室开放基金资助项目(101119,081214) (101119,081214)

原子能科学技术

OA北大核心CSCDCSTPCD

1000-6931

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