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塔里木盆地海相碳酸盐岩中有机酸盐的分析

孙敏卓 孟仟祥 郑建京 王国仓 房嬛 王作栋

中南大学学报(自然科学版)2013,Vol.44Issue(1):216-222,7.
中南大学学报(自然科学版)2013,Vol.44Issue(1):216-222,7.

塔里木盆地海相碳酸盐岩中有机酸盐的分析

Analysis of organic acid salts of marine carbonate rocks in Tarim Basin

孙敏卓 1孟仟祥 1郑建京 1王国仓 1房嬛 1王作栋1

作者信息

  • 1. 中国科学院 油气资源研究重点实验室,甘肃兰州,730000
  • 折叠

摘要

Abstract

A method was developed for the determination of the organic acid salts of marine carbonate rocks in Tarim Basin by the thermogravimetric/differential thermal (TG/DTA), infrared spectroscopy (IR) and gas chromatography/mass spectrometry (GC/MS).By analyzing the guide sample such as the stearic acid, the magnesium stearate, the calcium stearate and the calcium carbonate by TG/DTA, the temperature range where the organic acid was gasificated while the organic acid salt wasn't gasificated were defined, and thereby the experimental procedures for separating and extracting the organic acid salt from the carbonatite rock was designed.The results show that the organic acid salt exists in carbonatite rock by using the infrared spectroscopy and gas chromatography/mass spectrometry. The quantity of the organic acid salts of marine carbonate rocks in Tarim Basin is insignificantly correlated with the carbonate content of samples, but it is correlated with the types of sedimentary facies of samples, namely relative enrichment of the organic acid salts in sedimentary strata of the slope facies sedimentary environment.

关键词

海相碳酸盐岩/有机酸盐/红外光谱法/热重/差热法/气相色谱/质谱联用法

Key words

marine carbonate rocks/ organic acid salts/ infrared spectroscopy/ thermogravimetric/differential thermal/ gas chromatography/mass spectrometry

分类

天文与地球科学

引用本文复制引用

孙敏卓,孟仟祥,郑建京,王国仓,房嬛,王作栋..塔里木盆地海相碳酸盐岩中有机酸盐的分析[J].中南大学学报(自然科学版),2013,44(1):216-222,7.

基金项目

石油化工联合基金资助项目(40739902) (40739902)

中国科学院知识创新工程青年人才类重要方向研究项目(KZCX2-EW-QN112) (KZCX2-EW-QN112)

国家自然科学基金资助项目(41072106) (41072106)

中南大学学报(自然科学版)

OA北大核心CSCDCSTPCD

1672-7207

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