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双环己酮草酰二腙-CTMAB光度法测定铝合金中的铜

管英华 季振涛 杨超

巢湖学院学报Issue(6):43-45,3.
巢湖学院学报Issue(6):43-45,3.

双环己酮草酰二腙-CTMAB光度法测定铝合金中的铜

DETERMINATION OF COPPER IN ALUMINUM ALLOY BY SPRCTROPHOTOMETRY WITH BOD AND CTMAB

管英华 1季振涛 2杨超2

作者信息

  • 1. 合肥职业技术学院,安徽巢湖238000
  • 2. 巢湖学院化学化工与生命科学学院,安徽巢湖238000
  • 折叠

摘要

Abstract

The color reaction between dicyclohexanoneoxalyldihydrazone (BCO) and copper ( II ) had been studied, and determination method of trace copper in aluminum alloy by spectrophotometry was established. In the presence of surfactant CTMAB and in the NH3. H20-NH4C1 buffer medium, copper( Ⅱ ) and BCO forms a blue complex, the complex has a maximum absorption at 606 nm. Beers's law is obeyed in the range of 0-80 μg in the solution of 25 mL for copper( 11 ). The apparent molar absorptivity is 1.79104 L?mol-1?cm-1. The method was rapid and simple to determinate copper in aluminum alloy with satisfactory results.

关键词

双环已酮草酸二腙(BCO)/光度法/铝合金/

Key words

dicyclohexanoneoxalyldihydrazone(BCO)/spectrophotometry/aluminum alloy/copper

分类

化学化工

引用本文复制引用

管英华,季振涛,杨超..双环己酮草酰二腙-CTMAB光度法测定铝合金中的铜[J].巢湖学院学报,2012,(6):43-45,3.

巢湖学院学报

1672-2868

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