巢湖学院学报Issue(6):43-45,3.
双环己酮草酰二腙-CTMAB光度法测定铝合金中的铜
DETERMINATION OF COPPER IN ALUMINUM ALLOY BY SPRCTROPHOTOMETRY WITH BOD AND CTMAB
管英华 1季振涛 2杨超2
作者信息
- 1. 合肥职业技术学院,安徽巢湖238000
- 2. 巢湖学院化学化工与生命科学学院,安徽巢湖238000
- 折叠
摘要
Abstract
The color reaction between dicyclohexanoneoxalyldihydrazone (BCO) and copper ( II ) had been studied, and determination method of trace copper in aluminum alloy by spectrophotometry was established. In the presence of surfactant CTMAB and in the NH3. H20-NH4C1 buffer medium, copper( Ⅱ ) and BCO forms a blue complex, the complex has a maximum absorption at 606 nm. Beers's law is obeyed in the range of 0-80 μg in the solution of 25 mL for copper( 11 ). The apparent molar absorptivity is 1.79104 L?mol-1?cm-1. The method was rapid and simple to determinate copper in aluminum alloy with satisfactory results.关键词
双环已酮草酸二腙(BCO)/光度法/铝合金/铜Key words
dicyclohexanoneoxalyldihydrazone(BCO)/spectrophotometry/aluminum alloy/copper分类
化学化工引用本文复制引用
管英华,季振涛,杨超..双环己酮草酰二腙-CTMAB光度法测定铝合金中的铜[J].巢湖学院学报,2012,(6):43-45,3.