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外加纳米铜对钧瓷釉层显微结构及呈色的影响

郭家凡 贾会敏 法文君 冯铭华 张治军 郑直

硅酸盐通报2013,Vol.32Issue(2):225-230,6.
硅酸盐通报2013,Vol.32Issue(2):225-230,6.

外加纳米铜对钧瓷釉层显微结构及呈色的影响

Effect of Cu Element on the Microstructure and Coloring of Jun Glaze

郭家凡 1贾会敏 2法文君 1冯铭华 1张治军 1郑直3

作者信息

  • 1. 许昌学院表面微纳米材料研究所河南省微纳米能量储存与转换材料重点实验室,许昌461000
  • 2. 郑州大学化学系,郑州450000
  • 3. 河南大学教育部特种功能材料重点实验室,开封475004
  • 折叠

摘要

Abstract

The addition of water-soluble elemental copper nanoparticles can result in the significant changes of the coloring and the surface microstructures of the Jun porcelain glaze, after the same calcining process. By using X-ray diffraction, scanning electron microscope and energy dispersive X-ray spectroscopy, we systematically investigated the effects of the copper addition on the surface microstructuies and the coloring of the Jun porcelain glaze. The results show that the coloring of the Jun glaze changed from white to cyan or blue after the addition of elemental copper. Incidentally, the crystalline SiO2 were generally turned to be amorphous. Also, the additional copper can react with the carbon dioxide, oxygen, and water vapor generated in the glaze, and therefore stops the air vents getting into the glaze.

关键词

钧瓷/纳米铜/釉面状态/析晶/呈色

Key words

Jun porcelain/ nano-Cu/ surface properties/ crystallization/ coloring

分类

化学化工

引用本文复制引用

郭家凡,贾会敏,法文君,冯铭华,张治军,郑直..外加纳米铜对钧瓷釉层显微结构及呈色的影响[J].硅酸盐通报,2013,32(2):225-230,6.

基金项目

河南省杰出青年基金(104100510001)资助项目 (104100510001)

硅酸盐通报

OA北大核心CSCDCSTPCD

1001-1625

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