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P2O5对包钢高炉渣微晶玻璃析晶行为的影响

罗果萍 于文武 王艺慈 吴胜利 姜祺

硅酸盐通报2013,Vol.32Issue(2):283-288,6.
硅酸盐通报2013,Vol.32Issue(2):283-288,6.

P2O5对包钢高炉渣微晶玻璃析晶行为的影响

Effect of P2O5 on Crystallization Behavior of Glass-ceramics Prepared from Blast Furnace Slag of Baotou Steel

罗果萍 1于文武 2王艺慈 1吴胜利 1姜祺2

作者信息

  • 1. 内蒙古科技大学材料与冶金学院,包头014010
  • 2. 北京科技大学冶金与生态工程学院,北京100083
  • 折叠

摘要

Abstract

CaO-MgO-Al2O3-SiO2 glass-ceramics were prepared by melting method in this paper. Influence of nucleating agent P2O5(added by Na3(PO4) ·12H2O) on nucleation and crystallization temperature of basic glass was studied by DTA. The type, content and morphology of crystals were analyzed by XRD and SEM. The experimental results show that a small amount of P2O5 inhibits the crystallization process of the basic glass. The inhibition shows stronger with the increase of P2O5 content. But the bulk crystallization ability of basic glass is promoted when P2O5 content exceeds 4%. This effect becomes more obvious with the increase of P2O5 content. And the type and morphology of crystals change at the same time.

关键词

微晶玻璃/晶核剂/析晶/P2O5

Key words

glass-ceramics/ nucleating agent/ crystallization/ P2O5

分类

化学化工

引用本文复制引用

罗果萍,于文武,王艺慈,吴胜利,姜祺..P2O5对包钢高炉渣微晶玻璃析晶行为的影响[J].硅酸盐通报,2013,32(2):283-288,6.

基金项目

内蒙古自治区自然科学基金重大项目(2011ZD06),内蒙古高校重点研究项目(NJZZ11141) (2011ZD06)

硅酸盐通报

OA北大核心CSCDCSTPCD

1001-1625

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