化工进展2013,Vol.32Issue(2):373-380,8.DOI:10.3969/j.issn.1000-6613.2013.02.022
电化学还原CO2阴极材料研究进展
Progress of cathode materials for electrochemical reduction of carbon dioxide
摘要
Abstract
Electrochemical reduction of carbon dioxide is of great importance not only for the environment but also for the resource and economic benefit. Development of cathode materials for electrochemical reduction of carbon dioxide and researches on these electrode materials in aqueous, organic and ion-liquid media are reviewed in this paper, and their advantages and disadvantages are discussed. In aqueous media, adequate H+ is provided for the CO2 hydrogenation reaction with a comparatively easy process, but the product shows less obvious promise for fuel use. In organic solution, high efficiency is achieved while reaction mechanism follows complicated pathways. Ion-liquid is a new research field with a much lower overpotential for CO2 formation, nevertheless the products are much more complex and difficult to separate. A prospect for further developments in this field is presented, requiring deeper research on composite material and reaction interface.关键词
二氧化碳/电化学还原/阴极材料Key words
carbon dioxide/ electrochemical reduction/ cathode materials分类
化学化工引用本文复制引用
赵晨辰,何向明,王莉,郭建伟..电化学还原CO2阴极材料研究进展[J].化工进展,2013,32(2):373-380,8.基金项目
国家自然科学基金(50873050,51273103)及国家973计划(2011CB935902,2012CB215501)项目. (50873050,51273103)