化工进展2013,Vol.32Issue(2):394-399,6.DOI:10.3969/j.issn.1000-6613.2013.02.025
功能化离子液体-MDEA复配体系吸收CO2
Absorption of CO2 in aqueous mixtures of functionalized ionic liquids and MDEA
摘要
Abstract
Two functionalized ionic liquids (ILs) - tetraethylammonium alaninate ([N2222][Ala]) and tetraethylammonium serinate ([N2222][Ser]) were synthesized by using the one-step method and verified with IR and 1H NMR, and their glass transition temperature and thermal decomposition temperature were determined. The solubility of CO2 in aqueous blends of N-methyl-diethanolamine (MDEA) and these two ILs were carried out at 40 ℃ and the results showed that both of these two ILs had a positive effect on the absorption of CO2, increasing by 8.63% and 5.40%, respectively, when IL's concentration was 10%. Moreover, physical properties namely, density and viscosity of these mixed solutions were measured over a temperature range of 20℃ to 60 ℃ to provide basic data for further application of ILs.关键词
N-甲基二乙醇胺/离子液体/二氧化碳/吸收Key words
MDEA/ ionic liquid/ CO2/ absorption分类
化学化工引用本文复制引用
王占丽,徐凡,邢小林,任保增..功能化离子液体-MDEA复配体系吸收CO2[J].化工进展,2013,32(2):394-399,6.基金项目
河南省科技攻关项目(112101210200). (112101210200)