化学工程2013,Vol.41Issue(2):33-37,5.DOI:10.3969/j.issn.1005-9954.2013.02.008
AB-8大孔树脂对柴胡总黄酮的吸附行为研究
Adsorption behavior of AB-8 macroporous resin for total flavonoids in Bupleurum
徐祖伟 1于朝生 1窦烁1
作者信息
- 1. 东北林业大学理学院阻燃材料分子设计与制备黑龙江省重点实验室,黑龙江哈尔滨150040
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摘要
Abstract
The kinetics and thermodynamics of the adsorption of total flavonoids in Bupleurum by AB-8 macroporous resin were studied using the static adsorption method. The kinetics results show that the pseudo-second order kinetics model can better describe the whole adsorption process. The multicollinearity of curves fitted by the intra-particle diffusion model demonstrates that the adsorption rates at different stages are influenced by the pore size distribution. The thermodynamics results show that the adsorption process fits the Langmuir isothermal model in the studied temperature range. The thermodynamic properties,i. e. △GΘ <0,△HΘ = 10. 51 kJ/mol and ASΘ = 44. 15 J/(mol · K) , indicate that the adsorption process is spontaneous and endothermic.关键词
AB-8大孔树脂/柴胡/总黄酮/动力学/热力学Key words
AB-8 macroporous resin/ Bupleurum/ total flavonoids/ kinetics/ thermodynamics分类
化学化工引用本文复制引用
徐祖伟,于朝生,窦烁..AB-8大孔树脂对柴胡总黄酮的吸附行为研究[J].化学工程,2013,41(2):33-37,5.