化工学报2013，Vol.64Issue(3)：1022-1029,8.DOI:10.3969/j.issn.0438-1157.2013.03.033
TMPAC-AlCl3离子液体中恒电流电沉积铝
Constant current electrodeposition of aluminum from TMPAC-AlCl3 ionic liquids
摘要
Abstract
TMPAC-A1C13 ionic liquids with different molar ratios of TMPAC and A1C13 were synthesized, and their conductivities were measured at different temperatures. The study was performed by means of constant current electrolysis, and the effects of temperature, current density, stirring speed and toluene additive amount on the deposited aluminum layers were investigated. Conductivity of TMPAC-A1C13 ionic liquids reached a maximum with 1:2 molar ratio of TMPAC to A1C13 at 80℃. Better quality deposit and higher current efficiency could be achieved at the same temperature with current density of 20 mA·cm-2 and stirring speed of 500 r· min-1. Conductivity of the ionic liquid increased but voltage of the electrolytic cell decreased with the addition of toluene. A dense, bright, smooth and uniformly distributed deposit was obtained at current density of 23 mA·cm-2 when volume percent of toluene was 50%.关键词
铝/电沉积/离子液体/电导率/甲苯Key words
aluminum/ electrodeposition/ ionic liquid/ conductivity/ toluene分类
化学化工引用本文复制引用
尹小梅,徐联宾,单南南,崔节振,陈建峰..TMPAC-AlCl3离子液体中恒电流电沉积铝[J].化工学报,2013,64(3):1022-1029,8.基金项目
国家重点基础研究发展计划项目(2009CB219903) （2009CB219903）
国家自然科学基金项目(20971012,51172014) （20971012,51172014）
教育部留学回国人员科研启动基金项目(LX2009-04). （LX2009-04）
