首都师范大学学报（自然科学版）2013，Vol.34Issue(1)：27-30,4.
桥氧连结的氯化铁阴离子(Cl3Fe-O-FeCl3)2-同N,N'-二甲基联吡啶阳离子构成的配合物的合成与表征
Solvothermal Synthesis and Characterization of a (μ-Oxo) bis [trichloroferrate(Ⅲ)] Dianion-based Complex
摘要
Abstract
A ( μ - oxo)bis[ trichloroferrate(Ⅲ) ] dianion-based complex, formulated as ( bipy) ( Fe2OCl6) (bipy=N, N'-Dimethyl-4,4'-bipyridinium) ,has been prepared by solvothermal reactions of ferric chloride and 4 ,4'-bipyridine ligand in alcoholic solution. The complex contains an organic cation and a ( (μ-oxo) bis [ trichloroferrate ( Ⅲ)] dianion. The organic cationic was generated by N-heterocycles with alcohols, which coexists with anionic ferric halides. The complex crystallizes in the monoclinic system, space group P21/c with cell parameters, a = 1. 3064 (3) nm, b = 1.10367(2) nm, c =1.4775(3) nm, 0 = 107.32(3)°, V = 2. 0338(7) nm3.关键词
溶剂热法/三氯化铁/4,4'-联吡啶/桥连Key words
solvothermal/ferric chloride/4/4'-bipyridine/bridged bond分类
数理科学引用本文复制引用
安澜,钟丽娟,鲁晓明..桥氧连结的氯化铁阴离子(Cl3Fe-O-FeCl3)2-同N,N'-二甲基联吡啶阳离子构成的配合物的合成与表征[J].首都师范大学学报（自然科学版）,2013,34(1):27-30,4.基金项目
国家自然科学基金(NO.21193150,NO.20871085)资助项目. （NO.21193150,NO.20871085）
