高等学校化学学报2013，Vol.34Issue(3)：698-702,5.DOI:10.7503/cjcu20120680
网络互穿的固相微萃取聚乙烯醇复合涂层的制备
Preparation of Interpenetrating Network Polyvinyl Alcohol Composite Coatings for Solid-phase Microextraction
摘要
Abstract
PVA/SiO2 composite coatings which have the interpenetrating organic and inorganic cross-linked network were prepared by repeated freezing-thawing and sol-gel techniques. The structure and characterization of the composite membrane were determined by FTIR, TGA, SEM and gas chromatography. The composite coatings have good thermal stability (Td＞300℃ ) and good adherence activity that they are difficult shedding from coated glass or quartz fiber surface by chemical bonds. The performance of the coatings was tested by extraction of 1 -propanol, 1 - butanol, amyl alcohol and toluene. The fiber coatings proved to be selective for polar compounds containing hydroxyl groups. The relative standard deviation( RSD, n = 3) was less than 5%.关键词
聚乙烯醇/溶胶-凝胶法/冷冻-解冻法/固相微萃取Key words
Poly( vinyl alcohol) / Sol-gel method/ Freezing-thawing/ Solid-phase microextraction分类
化学化工引用本文复制引用
张梦娟,费旭,田晶,范叔奇,王一..网络互穿的固相微萃取聚乙烯醇复合涂层的制备[J].高等学校化学学报,2013,34(3):698-702,5.基金项目
国家自然科学基金(批准号:21204007)、辽宁省教育厅科学技术研究基金(批准号:L2011080)和辽宁省教育厅重点实验室基金(批准号:LS2010012)资助. （批准号:21204007）
