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硅烷偶联剂链长对纳米TiO2表面改性的影响

郝春静 湛含辉 王晓

表面技术2013,Vol.42Issue(2):10-13,4.
表面技术2013,Vol.42Issue(2):10-13,4.

硅烷偶联剂链长对纳米TiO2表面改性的影响

Effect of Chain Length of Silane Coupling Agent for Surface Modification of Nano-TiO2

郝春静 1湛含辉 1王晓1

作者信息

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摘要

Abstract

Nano-TiO2 particles were modified respectively by silane coupling agent KH570 and KH171 with different chain length. The influence of KH570 and KH171 on the graft modifying effect of Nano-TiO2 was studied by FT-IR, TG, TEM techniques. The results show that the organic chain length of silane coupling agent can produce space steric hindrance effect. It plays a key role on modification nanometer particles. TEM show that dispersion effect on modifying nano-TiO2 by long-chain silane coupling agent (KH570) is much better. TG and wettability experiments show conent of long-chain silane coupling agent KH570 is 10% , the coupling agent grafting rate and water contact angle is maximum, respectively 8.05% and 76.6°; FT-IR show that long-chain KH570 bond strength is much stronger than KH171.

关键词

硅烷偶联剂/链长/纳米TiO2/表面改性

Key words

silane coupling agent/ chain/ nano-TiO2/ surface modification

分类

化学化工

引用本文复制引用

郝春静,湛含辉,王晓..硅烷偶联剂链长对纳米TiO2表面改性的影响[J].表面技术,2013,42(2):10-13,4.

基金项目

江苏省水利科技项目(2012054) (2012054)

表面技术

OA北大核心CSCDCSTPCD

1001-3660

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