表面技术2013,Vol.42Issue(2):10-13,4.
硅烷偶联剂链长对纳米TiO2表面改性的影响
Effect of Chain Length of Silane Coupling Agent for Surface Modification of Nano-TiO2
摘要
Abstract
Nano-TiO2 particles were modified respectively by silane coupling agent KH570 and KH171 with different chain length. The influence of KH570 and KH171 on the graft modifying effect of Nano-TiO2 was studied by FT-IR, TG, TEM techniques. The results show that the organic chain length of silane coupling agent can produce space steric hindrance effect. It plays a key role on modification nanometer particles. TEM show that dispersion effect on modifying nano-TiO2 by long-chain silane coupling agent (KH570) is much better. TG and wettability experiments show conent of long-chain silane coupling agent KH570 is 10% , the coupling agent grafting rate and water contact angle is maximum, respectively 8.05% and 76.6°; FT-IR show that long-chain KH570 bond strength is much stronger than KH171.关键词
硅烷偶联剂/链长/纳米TiO2/表面改性Key words
silane coupling agent/ chain/ nano-TiO2/ surface modification分类
化学化工引用本文复制引用
郝春静,湛含辉,王晓..硅烷偶联剂链长对纳米TiO2表面改性的影响[J].表面技术,2013,42(2):10-13,4.基金项目
江苏省水利科技项目(2012054) (2012054)