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11-羧基十一烷基甲基硅油的合成及应用

姜佳美 李战雄 沈玲 丁晓玲

印染助剂2013,Vol.30Issue(4):31-35,5.
印染助剂2013,Vol.30Issue(4):31-35,5.

11-羧基十一烷基甲基硅油的合成及应用

Synthesis and application of carboxyl undecyl methyl silicone oil

姜佳美 1李战雄 1沈玲 1丁晓玲1

作者信息

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摘要

Abstract

Long chain carboxyl dichlorosilane monomer was synthesized by hydrosilylation using undecyle-nic acid and methyldichlorosilane as material, which was reacted with dimethyldichlorosilane and hexamethyld-isiloxane to prepare carboxyl undecyl methyl silicone oil with different molecular weight and different carboxyl content. The carboxyl silicone oil was mixed with amino silicone oil emulsion, and was applied on cotton fabric finishing. The influences of the molecular weight of carboxyl silicone oil, carboxyl content, the proportion ratio of carboxyl silicone oil and amino silicone oil on finishing effect were investigated. The results showed that the optimum finishing technology was: the molecular weight of carboxyl silicone oil was 6 000, carboxyl content was 12% and the proportion ratio of carboxyl silicone oil was 60%. The cotton fabric treated with the blended silicone oil had better softness and laundry resistance than that treated with amino silicone oil alone.

关键词

合成/羧基硅油/乳化/氨基硅油/柔软整理

Key words

synthesis/ carboxyl silicone oil/ emulsification/ amino silicone oil/ softening finishing

分类

化学化工

引用本文复制引用

姜佳美,李战雄,沈玲,丁晓玲..11-羧基十一烷基甲基硅油的合成及应用[J].印染助剂,2013,30(4):31-35,5.

印染助剂

OA北大核心CSTPCD

1004-0439

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