环境工程学报2013，Vol.7Issue(4)：1515-1521,7.
利用废弃物衍生燃料的热化学处理法制富含氢气合成气
Hydrogen-rich synthesis gas production via thermochemical of refuse derived fuel
摘要
Abstract
A detailed research of the major influencing factors on hydrogen-rich synthesis gas production during the thermochemical municipal solid waste ( MSW ) was carried out. The relationship between hydrogen generation characteritics and major factors was investigated. A detailed analysis about the components of MSW was made. MSW was pretreated into refuse derived fuel (RDF) to achieve a raw material with homogenization components for the following gasification experiments. RDF was employed to carry out a series of pyrolysis experiments, gasification experiments and steam gasification experiments at 700, 800 and 900t , respectively. The experimental results indicate that, by manufacturing MSW into RDF, not only the moisture content can be effectively reduced, but also their low heating value (LHV) can be increased nearly double. It also demonstrates that temperature and steam are key influencing factors, furthermore, it is confirmed that steam supply during gasification will promote hydrocarbons of waste to be decomposed into valuable gas compositions, such as CO and H2. However, temperature plays a dominate role in hydrogen generation. The higher temperature is, the more hydrogen can be achieved. It shows that a kind of synthesis gas containing the highest hydrogen concentration to 34. 13% can be generated from steam gasification process at 900℃,and the maximum LHV of gas to 14 509 kJ/ Nm3 can be achieved during the pyrolysis process at 800℃.关键词
城市生活垃圾/废弃物衍生燃料(RDF)/热解/气化/富含氢气合成气Key words
municipal solid waste/ refuse derived fuel (RDF) / pyrolysis/ gasification/ hydrogen-rich synthesis gas分类
资源环境引用本文复制引用
吴畏..利用废弃物衍生燃料的热化学处理法制富含氢气合成气[J].环境工程学报,2013,7(4):1515-1521,7.基金项目
国家自然科学基金资助项目(20976029) （20976029）
