Pt/CFMs电极的制备及其在甲醇电化学氧化中的性能研究OA北大核心CSCDCSTPCD
Platinum Nanoparticles Supported on Electrospinning-derived Carbon Fibrous Mats for Methanol Electrooxidation
应用物理吸附乙二醇还原法将Pt粒子负载于静电纺丝法制备的碳纳米纤维膜上(CFMs),构建电极Pt/CFMs,并用循环伏安法和计时安培法研究了电极Pt/CFMs在甲醇电化学氧化中的催化性能.结果表明,与用滴涂法构建的Pt/C-CFMs电极相比,电极Pt/CFMs催化氧化甲醇时,具有较高的催化活性、较好的稳定性和较好的耐中间产物毒化的能力.Pt/CFMs电极较好的催化性能可归因于纤维膜内碳纤维的连续性、碳纳米纤维膜较高的电导率以及Pt粒子与碳纤维间的…查看全部>>
A novel process was developed to prepare Pt nanoparticles on electrospinning-derived carbon fibrous mats (CFMs),which involved the physical adsorption of H2PtCl6 on the CFMs and the reduction of H2PtCl6 with ethylene glycol. The performance of the prepared Pt/CFMs electrodes for methanol electro-oxidation was investigated by cyclic voltammetry and chronoamperometry. The results demonstrate that Pt/CFMs electrodes exhibit higher electrocatalytic activity and …查看全部>>
李妙鱼;韩高义;杨斌盛
化学化工
静电纺丝碳纤维Pt粒子乙二醇甲醇电化学氧化
electrospinningcarbon nanofibersPt nanoparticlesethylene glycolmethanol electrooxidation
《山西大学学报(自然科学版)》 2013 (1)
碳复合纳米纤维及以其为载体的阳极电催化剂的制备、结构与性能研究
68-73,6
国家自然科学基金(2107311520604014)山西省自然科学基金(2012021021-32007021008)教育部新世纪优秀人才支持计划(NCET-10-0926)山西省回国留学人员科研项目(2011-003)
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