物理学报2013，Vol.62Issue(2)：185-190,6.DOI:10.7498/aps.62.023401
反应物NO的转动激发对反应N(4S)+NO(X2∏)→N2(X3∑g-)+O(3P)影响的立体动力学研究
Effect of rotational excitation of NO on the stereodynamics for the reaction N(4S)+NO(X2∏) → N2(X3∑g-)+O(3P)
摘要
Abstract
The stereodynamic properties of the reaction N (4S)+NO (X2Ⅱ) → N2 (X3Σg-)+O (3P) in different initial reagent rotational states are studied theoretically by using the quasiclassical trajectory method on two lowest 3A" and 3A' potential energy surfaces at a collision energy of 0.6 eV. The vector properties of different rotational states on the two potential energy surfaces are discussed in detail. The results indicate that the rotational excitation of NO has a considerable influence on the stereodynamic property of reaction occurring on the 3A' potential energy surface, which can be ascribed to the early barrier on this potential energy surface.关键词
准经典轨线/矢量相关/N+NO/转动激发Key words
quasiclassical trajectory/ vector correlations/ N+NO/ rotational excitation引用本文复制引用
马建军..反应物NO的转动激发对反应N(4S)+NO(X2∏)→N2(X3∑g-)+O(3P)影响的立体动力学研究[J].物理学报,2013,62(2):185-190,6.基金项目
国家自然科学基金(批准号:41075027)资助的课题. （批准号:41075027）
