固体火箭技术2013，Vol.36Issue(1)：67-72,78,7.DOI:10.7673/j.issn.1006-2793.2013.01.013
高能硼氢燃烧剂与固体推进剂常用组分相容性的DSC法研究
Compatibility of high energetic boron-hydrogen incendiary agent with some common components in solid propellant by means of DSC method
摘要
Abstract
The compatibility of high energetic boron-hydrogen incendiary agent (tetraethylammonium dodecahydrododecabo-rates,BHN) with some energetic components and inert materials in solid propellants was studied by means of DSC method and active energy transformation, among which glycidylazidopolymer (GAP) , cyclotrimethylenetrinitramine ( RDX) , cyelotetramethylenetet-ranitroamine ( HMX ) , lead 3-nitro-l , 2, 4-triazol-5-onate ( NTO-Pb) , hexanitrohexaazaisowurtzitane ( CL-20 ) , aluminum powder (Al ,particle size is 12. 18 μm) ,magnesium powder ( Mg,particle size is 44 -47 μm) ,3 ,4-dinitrofurzanfuroxan ( DNTF) and N-guanylurea-dinitramide (GUDN) were used as energetic components and polyoxytetramethylene-co-oxyethylene ( PET) , polyethylene glycol (PEG) ,addition product of hexamethylene diisocyanate and water (N-100) ,hydroxyl terminated polybutediene ( HT-PB) ,cupric adipate (AD-Cu) ,cupric 2,4-dihydroxy-benzoate (β-Cu) ,lead phthalate (ψ-Pb) ,carbon black (CB) ,aluminum oxide (A12O3) ,1,3-dimethyl-l ,3-diphenyl urea (C2) ,di-2-ethylhexyl sebacate (DOS) and potassium perchlorate (KP) were used as inert materials. The results show that the binary systems of BHN with NTO-Pb,CL-20,Al,Mg,PET,PEG,N-100,HTPB.CB, A12O3 ,C2 ,DOS and KP are compatible, BHN with GAP and HMX are slightly sensitive, BHN with AD-Cu ,β-Cu and ψ-Pb are sensitive, BHN with RDX.DNTF and GUDN are incompatible.关键词
物理化学/相容性/含能材料/差示扫描量热法(DSC)/高能硼氢燃烧剂Key words
physical chemistry compatibility/ energetic materials/ differential scanning calorimetry ( DSC) / high energetic bo- ron-hydrogen incendiary agent分类
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庞维强,胥会祥,廖林泉,石小兵,李洋,李勇宏,王晓飞..高能硼氢燃烧剂与固体推进剂常用组分相容性的DSC法研究[J].固体火箭技术,2013,36(1):67-72,78,7.基金项目
火炸药行业青年创新基金(HZY10). （HZY10）
