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DEA复配水溶液二氧化碳溶解度的测定实验

李小康 刘应书 张辉 魏广飞 李虎 张四宗

化工进展2013,Vol.32Issue(4):769-773,778,6.
化工进展2013,Vol.32Issue(4):769-773,778,6.DOI:10.3969/j.issn.1000-6613.2013.04.007

DEA复配水溶液二氧化碳溶解度的测定实验

Experimental study of the carbon dioxide absorption in mixtures of aqueous DEA and others

李小康 1刘应书 1张辉 1魏广飞 1李虎 1张四宗1

作者信息

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摘要

Abstract

A device was designed to measure the solubility of CO2 in the aqueous amine in this research. The following data were obtained, carbon dioxide solubility in 2 mol/L aqueous DEA at 308 K、318 K、 328 K、 358 K under CO2 partial pressure of 0—150 kPa. Meanwhile, mixtures of additives such as DETA, MDEA, AEE as well as SG and aqueous DEA were compounded and the solubility of CO2 in such mixtures were measured. The molar ratio of DEA and the additive in the mixture was 3 : 1 and the total concentration of the amine remained at 2 mol/L. The results showed that elevating the partial pressure of CO2 may contribute to the increase of the solubility in the aqueous DEA, and the temperature played a reverse role. Impacts of different additives on the solubility of CO2 was presented to be DETA > AEE > SG > MDEA.

关键词

DEA复配溶液/二氧化碳/平衡溶解度

Key words

aqueous mixtures of DEA/carbon dioxide(CO2)/equilibrium solubility

分类

化学化工

引用本文复制引用

李小康,刘应书,张辉,魏广飞,李虎,张四宗..DEA复配水溶液二氧化碳溶解度的测定实验[J].化工进展,2013,32(4):769-773,778,6.

基金项目

国家863计划(2012AA101800). (2012AA101800)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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