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Ce掺杂TiO2纳米复合薄膜的制备及光催化活性

康俊龙 姚兰芳 杨松林 王亚琴 梁兴 黄艳

人工晶体学报2013,Vol.42Issue(4):671-676,6.
人工晶体学报2013,Vol.42Issue(4):671-676,6.

Ce掺杂TiO2纳米复合薄膜的制备及光催化活性

Preparation and Photocatalytic Activity of Ce-doped TiO2 Nanocomposite Films

康俊龙 1姚兰芳 2杨松林 3王亚琴 3梁兴 3黄艳3

作者信息

  • 1. 上海理工大学理学院,上海200093
  • 2. 上海市特殊人工微结构材料与技术重点实验室,上海200092
  • 折叠

摘要

Abstract

Ce-doped TiO2 nanocomposite films with the template of CTAB were prepared by the dip-coating method based on the sol-gel process.The samples were characterized by XRD, N2 adsorption-desorption, UV-Vis, SEM, XPS.The results show that the dopant Ce existed on surface of TiO2 as Ce4+ and Ce3 +.And the CTAB protected the TiO2 particles from aggregating and restrained the transform of anatase structure to rutile structure.UV-Vis absorbance spectra showed that under the template of CTAB the absorption band edge of Ce-doped TiO2 composite nano-films exhibited a red shift compared with that of pure TiO2 nano-films.And it exhibited a higher photocatalytic activity compared with the Ce-doped TiO2 without CTAB.Under an ultraviolet lamp irradiation, CTAB(1.0% )/Ce(1.0% )-TiO2 composite nano-film had the highest photocatalytic activity calcined at 500 ℃ and the degradation rate of the film is 95.3% after 120 min.

关键词

溶胶-凝胶法/TiO2/纳米复合薄膜/甲基橙/光催化

Key words

sol-gel method/ TiO2/ nanocomposite film/ methyl orange/ photocatalysis

分类

数理科学

引用本文复制引用

康俊龙,姚兰芳,杨松林,王亚琴,梁兴,黄艳..Ce掺杂TiO2纳米复合薄膜的制备及光催化活性[J].人工晶体学报,2013,42(4):671-676,6.

基金项目

上海市特殊人工徽结构材料与技术重点实验室(ammt20011A-4)资助项目 (ammt20011A-4)

上海市2012年度"大学生创新创业训练计划"(201210252110) (201210252110)

人工晶体学报

OA北大核心CSCDCSTPCD

1000-985X

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