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PP/EVAL/PP-g-MAH动态硫化体系的结构与性能研究

赵苹 夏英 翁伟明 王希锋 郭慧敏 段效威 孙强

塑料科技2013,Vol.41Issue(5):53-56,4.
塑料科技2013,Vol.41Issue(5):53-56,4.

PP/EVAL/PP-g-MAH动态硫化体系的结构与性能研究

Study on the Structure and Property of PP/EVAL/PP-g-MAH Dynamically Vulcanized Blends

赵苹 1夏英 1翁伟明 1王希锋 1郭慧敏 1段效威 1孙强1

作者信息

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摘要

Abstract

The mechanical property, morphology, crystallography and dynamic mechanical property of propylene/saponified ethylene-vinyl acetate copolymer/maleic anhydride graft polypropylene (PP/EVAL/PP-g-MAH) dynamically vulcanized blends. The results show that: the mechanical properties and mold flow rate (MFR) of PP/EVAL dynamically vulcanized blend improve with the addition of PP-g-MHA significantly. The impact strength of PP/EVAL/PP-g-MAH (80/20/8) dynamically vulcanized blend increases by 179.6% compared with the PP/EVAL(80/20) dynamically vulcanized blend, reaches to 74.1 kJ/m2, and the MFR is 13.4 g/10min. The dispersion effect of the disperse phase and the compatibility between PP phase and EVAL phase improves with the addition of PP-g-MAH, and the formation of α crystallization and β crystallization of PP in the PP/EVAL dynamically vulcanized blend promotes. Tg of PP component of the PP/EVAL dynamically vulcanized blend shifts to lower tempetature with the addition of PP-g-MAH.

关键词

聚丙烯/皂化乙烯-乙酸乙烯共聚物/马来酸酐接枝聚丙烯/结构/性能

Key words

PP/ Saponified ethylene-vinyl acetate copolymer/ PP-g-MAH/ Structure/ Property

分类

化学化工

引用本文复制引用

赵苹,夏英,翁伟明,王希锋,郭慧敏,段效威,孙强..PP/EVAL/PP-g-MAH动态硫化体系的结构与性能研究[J].塑料科技,2013,41(5):53-56,4.

基金项目

大连市科技攻关项目(2012A17GX130) (2012A17GX130)

国家级大学生创新创业训练计划项目(201210152010) (201210152010)

塑料科技

OA北大核心CSTPCD

1005-3360

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