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柠檬酸对合成聚丁二酸丁二醇酯性能的影响

李晋 刘俊红 黄勇

塑料科技2013,Vol.41Issue(5):79-82,4.
塑料科技2013,Vol.41Issue(5):79-82,4.

柠檬酸对合成聚丁二酸丁二醇酯性能的影响

Effect of Critical Acid on the Property of Synthesized Poly(butylene succinate)

李晋 1刘俊红 1黄勇1

作者信息

  • 折叠

摘要

Abstract

Branched or slightly crosslinked poly(butylene succinate) was synthesized by direct melt polycondensation of succinic acid, 1,4-butanediol and critical acid. The structure of c-PBS was characterized by 1HNMR. The properties of PBS were characterized using Ubbelohde viscometer, DSC and test instrument of mechanical property. The results show that: the gelation, intrinsic viscosity, tensile strength and tensile modulus of PBS increase with the increasing of critic acid content, but the elongation at break decreases. The introduction of critical acid is in favor of the molecular chain crystallization of PBS, and also can make the crystallization temperature increase.

关键词

聚丁二酸丁二醇脂/柠檬酸/拉伸性能

Key words

Poly(butylene succinate)/ Critical acid/ Tensile property

分类

化学化工

引用本文复制引用

李晋,刘俊红,黄勇..柠檬酸对合成聚丁二酸丁二醇酯性能的影响[J].塑料科技,2013,41(5):79-82,4.

基金项目

泸州市重点科技项目[2010-S-22(2/3)] (2/3)

塑料科技

OA北大核心CSTPCD

1005-3360

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