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萃取精馏分离D40溶剂油中C8-C12异构烷烃

刘海 黎四芳

化学工程2013,Vol.41Issue(3):29-31,36,4.
化学工程2013,Vol.41Issue(3):29-31,36,4.DOI:10.3969/j.issn.1005-9954.2013.03.007

萃取精馏分离D40溶剂油中C8-C12异构烷烃

Separation of isoparaffins(C8-C12) from D40 oil by extractive distillation

刘海 1黎四芳1

作者信息

  • 1. 厦门大学化学化工学院,福建厦门361005
  • 折叠

摘要

Abstract

In the separation of isoparaffins and naphthenes by extractive distillation of D40 oil from Nanjing refinery, several entrainers including sulfolane, dimethyl phthalate and triethylene glycol, as well as their mixtures were applied and studied, among which sulfolane has the best selectivity to isoparaffins, and the mass fraction of isoparaffins in vapour phase from D40 oil is increased from 16.65% to 27.51% as the volume ratio of solvent to oil is 5:1 ,and the relative volatility is 1.151. Based on the study of single solvent,the effects of using mixed entrainers with different components on the relative volatilities and separation results were also investigated. The relative volatility of isoparaffins to naphthenes was promoted to 2. 895 by using the mixture of sulfolane and dimethy phthalate ( volume ratio 1:1) as an entrainer.

关键词

溶剂油/萃取精馏/异构烷烃

Key words

solvent oil/ extractive distillation/ isoparaffin

分类

化学化工

引用本文复制引用

刘海,黎四芳..萃取精馏分离D40溶剂油中C8-C12异构烷烃[J].化学工程,2013,41(3):29-31,36,4.

化学工程

OA北大核心CSCDCSTPCD

1005-9954

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