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新型光电子源离子迁移谱在检测四氯化碳中的应用

苏得生 牛文琪 刘升 沈成银 黄超群 王鸿梅 江海河 储焰南

量子电子学报2013,Vol.30Issue(2):138-145,8.
量子电子学报2013,Vol.30Issue(2):138-145,8.DOI:10.3969/j.issn.1007-5461.2013.02.003

新型光电子源离子迁移谱在检测四氯化碳中的应用

Detection of tetrachloromethane by a new photoemission ion mobility spectrometry

苏得生 1牛文琪 2刘升 1沈成银 1黄超群 1王鸿梅 1江海河 1储焰南1

作者信息

  • 1. 中国科学院安徽光学精密机械研究所环境光谱学研究室,安徽合肥 230031
  • 2. 安徽农业大学理学院,安徽合肥 230036
  • 折叠

摘要

Abstract

With a photoelectron source induced by ultraviolet radiation on mental surface, a photoemission ion mobility spectrometry (PE-IMS) was set up, which can be used to detect halide since halide has a good ability to attach electron. Using CCU sample, the evolutions of the ion intensity, full width at half maximum and resolution versus drift electric field, ion gate pulse width and ion gate voltage were obtained, and the reasons for the evolutions were analyzed simply. Taking into account both ion intensity and resolution, optimized experimental parameters were obtained. The PE-IMS has a limit of detection at 4 ppb for CCU and its measurable linear dynamics range is over two orders of magnitude in the optimized experimental parameters.

关键词

光谱学/离子迁移谱/光电效应/光电子源/四氯化碳

Key words

spectroscopy/ ion mobility spectrometry/ photoemission/ photoelectron source/ tetrachloromethane

分类

化学化工

引用本文复制引用

苏得生,牛文琪,刘升,沈成银,黄超群,王鸿梅,江海河,储焰南..新型光电子源离子迁移谱在检测四氯化碳中的应用[J].量子电子学报,2013,30(2):138-145,8.

基金项目

国家自然科学基金(20907054)、中国科学院创新工程重要方向项目(KGCX2-YW-917) (20907054)

量子电子学报

OA北大核心CSCDCSTPCD

1007-5461

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