安徽农业科学2013，Vol.41Issue(10)：4238-4241,4349,5.
芦丁在石墨烯修饰电极上的电化学行为及其灵敏检测
Electrochemical Behavior and Sensitive Detection of Rutin on Graphene Modified Electrode
摘要
Abstract
The aim was to study the electrochemical behavior of rutin on the graphene modified electrode and develop the corresponding detection method.[Method] Amino functionalized graphene was prepared with a chemical reduction method and was used to fabricate the sensitive rutin electrochemical sensor.Cycle voltammetry and difference pulse method were used to study electrochemical behavior of rutin on modified electrode,and difference pulse voltammetry was adopted to determine rutin.[Result] Due to the high special surface area and electrical conductivity of graphene,rutin exhibited an enhanced electrochemical activity in the novel sensor.The study of electrode reaction kinetics indicated that rutin undr went a surface-controlled quasi-reversible process.Under the optimized experimental condition,the fabricated sensor displayed excellent analytical performance for rutin detection from 2.0 × 10-8 to 1.0 × 10-5 mol/L with a low detection limit of 1.0 × 10-8 mol/L at 3σ.[Conclusion] The proposed electrochemical sensor exhibited good selectivity and stability,and it could be used for real samples.关键词
芦丁/石墨烯/修饰电极/差示脉冲/灵敏检测Key words
Rutin/ Graphene / Modified electrode/ Differential pulsevoltammetry / Sensitive detection分类
农业科技引用本文复制引用
刘坤平,李惠茗,何钢,颜军,郭晓强,赵琦,苟小军..芦丁在石墨烯修饰电极上的电化学行为及其灵敏检测[J].安徽农业科学,2013,41(10):4238-4241,4349,5.基金项目
成都大学校基金(2012XJZ12). （2012XJZ12）
